Preheat oven to 325F and line four 6 inch cake pans with parchment paper. If you are greasing the pans with spray, make sure to NOT overspray otherwise the sides/edges will brown/crisp up because of the excess fat from the spray.
In a small bowl, mix together the instant coffee granules and water until the granules are fully dissolved. Set aside.
In a medium-sized bowl, whisk together the cake flour, baking soda, and salt. Set aside.
In a medium-sized bowl or the bowl of a stand mixer fitted with the paddle attachment, beat the butter and oil together on high speed until completely combined. This will only happen if the butter is fully at room temperature. About 3-4 minutes.
With the mixer on low speed, stream in the granulated sugar then beat on medium speed until combined and fluffy. 1-2 minutes.
Add the eggs, one at a time, mixing well on low speed in between each addition, scraping down the sides and bottom of the bowl as necessary. I normally scrape the sides and bottom after every egg addition. Add the vanilla extract and coffee mixture and mix on low-medium speed until combined.
With the mixer on low, add half of the dry ingredients. Once almost fully incorporated, add half of the milk and mix until almost combined. Repeat this with the other halves of the dry ingredients and the milk. Do not over mix.
Divide the batter evenly amongst the four cake pans. Bake the cakes for 30-35 minutes until a toothpick inserted into the center of the cake comes out clean. The edges of the cake will be slightly pulling away from the pan. Let cool in the pan for 10-15 minutes, then transfer to a cooling rack to cool completely.